Fast and mild palladium(II)-catalyzed 1,4-oxidation of 1,3-dienes via activation of molecular oxygen with a designed cobalt(II) porphyrin

被引：13

作者：

Verboom, RC ^{[1
]}

Slagt, VF ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 10期

关键词：

D O I：

10.1039/b417758d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a Co(porphyrin)-amide ligand, 2, in the palladium(II)-catalyzed 1,4-diacetoxylation of conjugated dienes under O-2 results in aerobic oxidation. The catalyst was highly active under O-2, and the 1,4-diacetoxylation reaction could also be performed under air.

引用

页码：1282 / 1284

页数：3

共 19 条

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