Fast and mild palladium(II)-catalyzed 1,4-oxidation of 1,3-dienes via activation of molecular oxygen with a designed cobalt(II) porphyrin

被引：13

作者：

Verboom, RC ^{[1
]}

Slagt, VF ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 10期

关键词：

D O I：

10.1039/b417758d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a Co(porphyrin)-amide ligand, 2, in the palladium(II)-catalyzed 1,4-diacetoxylation of conjugated dienes under O-2 results in aerobic oxidation. The catalyst was highly active under O-2, and the 1,4-diacetoxylation reaction could also be performed under air.

引用

页码：1282 / 1284

页数：3

共 19 条

[11] Oxygen-promoted Pd(II) catalysis for the coupling of organoboron compounds and olefins
Jung, YC
Mishra, RK
Yoon, CH
Jung, KW
[J]. ORGANIC LETTERS, 2003, 5 (13) : 2231 - 2234
[12] SYNTHESIS OF UNSATURATED LACTONES VIA PALLADIUM-CATALYZED CYCLIZATION OF ALKENOIC ACIDS
LAROCK, RC
HIGHTOWER, TR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (20) : 5298 - 5300
[13] Elucidating the significance of β-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols
Mueller, JA
Goller, CP
Sigman, MS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) : 9724 - 9734
[14] Palladium(II)-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen
Nishimura, T
Onoue, T
Ohe, K
Uemura, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (18) : 6750 - 6755
[15] Palladium-catalyzed oxidation of primary and secondary allylic and benzylic alcohols
Peterson, KP
Larock, RC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10) : 3185 - 3189
[16] Application of O-2-DMSO as reoxidant in the Pd(II)-catalyzed 1,4-oxidation of 5-substituted 1,3-cyclohexadienes
Ronn, M
Andersson, PG
Backvall, JE
[J]. ACTA CHEMICA SCANDINAVICA, 1997, 51 (6-7): : 773 - 777
[17] COORDINATING PROPERTIES OF THE AMIDE BOND - STABILITY AND STRUCTURE OF METAL-ION COMPLEXES OF PEPTIDES AND RELATED LIGANDS
SIGEL, H
MARTIN, RB
[J]. CHEMICAL REVIEWS, 1982, 82 (04) : 385 - 426
[18] Palladium-catalyzed oxidative wacker cyclizations in nonpolar organic solvents with molecular oxygen: A stepping stone to asymmetric aerobic cyclizations
Trend, RM
Ramtohul, YK
Ferreira, EM
Stoltz, BM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (25) : 2892 - 2895
[19] New chiral diamide ligands containing redox-active hydroquinone groups.: Synthesis and results in the palladium(II)-catalyzed 1,4-diacetoxylation of 1,3-dienes
Verboom, RC
Plietker, BJ
Bäckvall, JE
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (02) : 508 - 517

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