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Automated parallel synthesis of MADIX (Co)Polymers

被引：40
作者：
Chapon, P
Mignaud, C
Lizarraga, G
Destarac, M
机构：
[1] Rhone Poulenc Rech, Ctr Rech Aubervilliers, F-93308 Aubervilliers, France
[2] Rhodia Inc, Cranbury Res Technol Ctr, Cranbury, NJ 08512 USA
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 01期
关键词：
block copolymers; libraries; MADIX; parallel synthesis; radical polymerization;
D O I：
10.1002/marc.200390016
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An automated parallel synthetic approach has been developed for synthesizing polymer libranes by the Macromolecular Design via the Interchange of xanthates (MADX) process. The experiment set-up, parallel polymerizations, characterization, and reproducibility tests are detailed. Examples of acrylic diblock copolymers systhesized in this way are given.
引用
收藏
页码：87 / 91
页数：5
相关论文
共 26 条
[1]   High-throughput synthesis of nanoscale materials:: Structural optimization of functionalized one-step star polymers [J].
Bosman, AW ;
Heumann, A ;
Klaerner, G ;
Benoit, D ;
Fréchet, JMJ ;
Hawker, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) :6461-6462
[2]  
Brocchini S, 1998, J BIOMED MATER RES, V42, P66, DOI 10.1002/(SICI)1097-4636(199810)42:1<66::AID-JBM9>3.0.CO
[3]  
2-M
[4]   A combinatorial approach for polymer design [J].
Brocchini, S ;
James, K ;
Tangpasuthadol, V ;
Kohn, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4553-4554
[5]  
Charmot D, 2000, MACROMOL SYMP, V150, P23, DOI 10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO
[6]  
2-E
[7]  
CHARMOT D, 2001, POLYM PREPR AM CHEM, V42, P627
[8]  
Corpart P., 1998, Patent No. 9858974
[9]   Xanthates as chain-transfer agents in controlled radical polymerization (MADIX):: Structural effect of the O-alkyl group [J].
Destarac, M ;
Bzducha, W ;
Taton, D ;
Gauthier-Gillaizeau, I ;
Zard, SZ .
MACROMOLECULAR RAPID COMMUNICATIONS, 2002, 23 (17) :1049-1054
[10]   Macromolecular design via the interchange of xanthates (MADIX): Polymerization of styrene with O-ethyl xanthates as controlling agents [J].
Destarac, M ;
Brochon, C ;
Catala, JM ;
Wilczewska, A ;
Zard, SZ .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2002, 203 (16) :2281-2289
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