Automated parallel synthesis of MADIX (Co)Polymers

被引:40
作者
Chapon, P
Mignaud, C
Lizarraga, G
Destarac, M
机构
[1] Rhone Poulenc Rech, Ctr Rech Aubervilliers, F-93308 Aubervilliers, France
[2] Rhodia Inc, Cranbury Res Technol Ctr, Cranbury, NJ 08512 USA
关键词
block copolymers; libraries; MADIX; parallel synthesis; radical polymerization;
D O I
10.1002/marc.200390016
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An automated parallel synthetic approach has been developed for synthesizing polymer libranes by the Macromolecular Design via the Interchange of xanthates (MADX) process. The experiment set-up, parallel polymerizations, characterization, and reproducibility tests are detailed. Examples of acrylic diblock copolymers systhesized in this way are given.
引用
收藏
页码:87 / 91
页数:5
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