MELAMINE HYDROGEN PEROXIDE (MHP): NOVEL AND EFFICIENT REAGENT FOR THE CHEMO- AND HOMOSELECTIVE AND TRANSITION METAL-FREE OXIDATION OF THIOLS AND SULFIDES

被引：39

作者：

Chehardoli, Gholamabbas ^{[1
]}

Zolfigol, Mohammad Ali ^{[2
]}

机构：

[1] Hamedan Univ Med Sci, Sch Pharm, Hamadan 65178, Iran

[2] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 01期

关键词：

Disulfides; homoselective oxidation; melamine hydrogen peroxide; sulfoxides; transition metal-free oxidation; SILICA SULFURIC-ACID; SELECTIVE OXIDATION; HETEROGENEOUS SYSTEM; SOLVENT-FREE; CORRESPONDING DISULFIDES; SULFOXIDES; MILD; SULFONES; CONVENIENT; ACID/NANO2;

D O I：

10.1080/10426500902758386

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Melamine hydrogen peroxide (MHP) as a novel hydrogen peroxide adduct was easily prepared. Both chemo- and homoselective oxidation of thiols and sulfides to their corresponding disulfides and sulfoxides occurred by using MHP in moderate to excellent yields. AlCl3 acts as a suitable activator in the oxidation of sulfides with MHP.

引用

页码：193 / 203

页数：11

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[51] An efficient method for production and storage of unstable S-nitrosothiols under mild and heterogeneous condition with sodium nitrite and oxalic acid dihydrate [J].