L-proline catalyzed asymmetric transfer aldol reaction between diacetone alcohol and aldehydes

被引：56

作者：

Chandrasekhar, S ^{[1
]}

Narsihmulu, C ^{[1
]}

Reddy, NR ^{[1
]}

Sultana, SS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 21期

关键词：

D O I：

10.1039/b409053p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate for the first time, L-proline as a chiral catalyst for transfer aldol reaction between aldehydes and diacetone alcohol.

引用

页码：2450 / 2451

页数：2

共 25 条

[1]

CARREIRA EM, 1999, COMPREHENSIVE ASYMME, V3, P998

[2] Asymmetric aldol reactions in poly(ethylene glycol) catalyzed by L-proline [J].

Chandrasekhar, S ;

Narsihmulu, C ;

Reddy, NR ;

Sultana, SS .

TETRAHEDRON LETTERS, 2004, 45 (23) :4581-4582

[3]

Chowdari NS, 2003, SYNLETT, P1906

[4] Direct organocatalytic aldol reactions in buffered aqueous media [J].

Córdova, A ;

Notz, W ;

Barbas, CF .

CHEMICAL COMMUNICATIONS, 2002, (24) :3024-3025

[5] Zn-proline catalyzed direct aldol reaction in aqueous media [J].

Darbre, T ;

Machuqueiro, M .

CHEMICAL COMMUNICATIONS, 2003, (09) :1090-1091

[6] Asymmetric catalysis of aldol reactions with chiral Lewis bases [J].

Denmark, SE ;

Stavenger, RA .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :432-440

[7]

Groger H, 1998, CHEM-EUR J, V4, P1137

[8] Proline-catalyzed direct asymmetric aldol reactions [J].

List, B ;

Lerner, RA ;

Barbas, CF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) :2395-2396

[9] Phosphine catalyzed aldol reaction between ketene silyl acetals and aldehydes: nucleophilic O-Si and C-Si bond cleavage by phosphines [J].

Matsukawa, S ;

Okano, N ;

Imamoto, T .

TETRAHEDRON LETTERS, 2000, 41 (01) :103-107

[10] CYANO GROUP TRANSFER OF ACETONE CYANOHYDRIN TO ALDEHYDE MEDIATED BY TITANIUM ALKOXIDE AND ALUMINUM ALKYLS [J].

MORI, A ;

KINOSHITA, K ;

OSAKA, M ;

INOUE, S .

CHEMISTRY LETTERS, 1990, (07) :1171-1172

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