Chiral channel-like cavity which is tunable via changes in 21-column packing structure

被引:12
作者
Imai, Yoshitane
Kawaguchi, Kakuhiro
Asai, Katuzo
Sato, Tomohiro
Kuroda, Reiko
Matsubara, Yoshio
机构
[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
[2] JST, ERATO, SORST, Kuroda Chriromorphol Team,Meguro Ku, Tokyo 1530041, Japan
[3] Univ Tokyo, Grad Sch Arts & Sci, Dept Life Sci, Meguro Ku, Tokyo 1538902, Japan
来源
CRYSTENGCOMM | 2007年 / 9卷 / 06期
关键词
D O I
10.1039/b705641a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A complex with a chiral channel-like cavity which can incorporate various n-alkyl alcohols and reversibly discharge and adsorb them, was successfully formed by combining chiral 1,2-diphenylethylenediamine ((1S,2S)-1) and biphenylacetic acid (2).
引用
收藏
页码:467 / 470
页数:4
相关论文
共 23 条
[1]   Enantioselective inclusion of (R)-phenylglycyl-(R)-phenylglycine with benzyl methyl sulfoxides [J].
Akazome, M ;
Hirabayashi, A ;
Ogura, K .
TETRAHEDRON, 2004, 60 (52) :12085-12093
[2]   Sheet structure of an L,D-dipeptide aggregate:: Inclusion compounds of (S)-phenylglycyl-(R)-phenylglycine with amides [J].
Akazome, M ;
Senda, K ;
Ogura, K .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (25) :8885-8889
[3]   Enantiomeric recognition of alkyl phenyl sulfoxides by crystalline (R)-phenylglycyl-(R)-phenylglycine [J].
Akazome, M ;
Noguchi, M ;
Tanaka, O ;
Sumikawa, S ;
Uchida, T ;
Ogura, K .
TETRAHEDRON, 1997, 53 (25) :8315-8322
[4]   Enantioselective inclusion of methyl phenyl sulfoxides and benzyl methyl sulfoxides by (R)-phenylglycyl-(R)-phenylglycine and the crystal structures of the inclusion cavities [J].
Akazome, M ;
Ueno, Y ;
Ooiso, H ;
Ogura, K .
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (01) :68-76
[5]   Photoexcited triplets of nitrodiphenylpolyenes hosted in channel cavities.: A time resolved EPR study [J].
Barbon, A ;
Bortolus, M ;
Brustolon, M ;
Maniero, AL ;
Zanrè, R .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (09) :2396-2402
[6]   Diffusive escape and reentry through a channel in the cavity wall [J].
Berezhkovskii, AM ;
Barzykin, A .
CHEMICAL PHYSICS LETTERS, 2004, 383 (1-2) :6-10
[7]  
HOLLINGSWORTH MD, 1996, COMPREHENSIVE SUPRAM, V6
[8]   Successive optical resolution of two compounds by one enantiopure compound [J].
Imai, Y ;
Takeshita, M ;
Sato, T ;
Kuroda, R .
CHEMICAL COMMUNICATIONS, 2006, (10) :1070-1072
[9]   Efficient optical resolution of secondary alkyl alcohols by chiral supramolecular hosts [J].
Imai, Y ;
Sato, T ;
Kuroda, R .
CHEMICAL COMMUNICATIONS, 2005, (26) :3289-3291
[10]   Development of a chiral host system tunable via changes in a 21-column packing structure [J].
Imai, Yoshitane ;
Kawaguchi, Kakuhiro ;
Sato, Tomohiro ;
Kuroda, Reiko ;
Matsubara, Yoshio .
TETRAHEDRON LETTERS, 2006, 47 (45) :7885-7888