Mesoporous hybrid materials containing two transition metal ions, one in the framework, the other in the channel pores

被引：43

作者：

Corriu, RJP ^{[1
]}

Mehdi, A ^{[1
]}

Reyé, C ^{[1
]}

Thieuleux, C ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR CNRS 5637, F-34095 Montpellier 5, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b303492p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous hybrid materials containing bridged metal cyclam moieties in the silicate framework were synthesized by using triblock copolymer F127 as template and SiH3 as hydrolysable terminal groups; grafting of a metal-cyclam precursor in the channel pores led to materials containing two different strongly chelated transition metal ions in two steps.

引用

页码：1564 / 1565

页数：2

共 19 条

[1] Periodic mesoporous organosilicas with organic groups inside the channel walls
Asefa, T
MacLachlan, MJ
Coombs, N
Ozin, GA
[J]. NATURE, 1999, 402 (6764) : 867 - 871
[2] Novel bifunctional periodic mesoporous organosilicas, BPMOs: Synthesis, characterization, properties and in-situ selective hydroboration-alcoholysis reactions of functional groups
Asefa, T
Kruk, M
MacLachlan, MJ
Coombs, N
Grondey, H
Jaroniec, M
Ozin, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) : 8520 - 8530
[3] COMPLEXES OF POLYAZA MACROCYCLES BEARING PENDENT COORDINATING GROUPS
BERNHARDT, PV
LAWRANCE, GA
[J]. COORDINATION CHEMISTRY REVIEWS, 1990, 104 (02) : 297 - 343
[4] Amine-functionalized periodic mesoporous organosilicas
Burleigh, MC
Markowitz, MA
Spector, MS
Gaber, BP
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (12) : 4760 - 4766
[5] New Route to Hybrid Materials: Rhodium Complex and Fluoride Ion Catalysed Hydrolysis of Hydrogenosilanes
Corriu, Robert J. P.
Moreau, Joel J. E.
Man, Michel Wong Chi
[J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) : 87 - 91
[6] Dubois G, 2001, ANGEW CHEM INT EDIT, V40, P1087, DOI 10.1002/1521-3773(20010316)40:6<1087::AID-ANIE10870>3.0.CO
[7] 2-O
[8] First organic-inorganic hybrid materials with controlled porosity incorporating cyclam units
Dubois, G
Corriu, RJP
Reyé, C
Brandès, S
Denat, F
Guilard, R
[J]. CHEMICAL COMMUNICATIONS, 1999, (22) : 2283 - 2284
[9] Glatter O., 1982, SMALL ANGLE XRAY SCA, P32
[10] Synthesis of large-pore phenylene-bridged mesoporous organosilica using triblock copolymer surfactant
Goto, Y
Inagaki, S
[J]. CHEMICAL COMMUNICATIONS, 2002, (20) : 2410 - 2411

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