Electromechanical properties of Nd-doped Bi4Ti3O12 films:: A candidate for lead-free thin-film piezoelectrics

被引:161
作者
Maiwa, H
Iizawa, N
Togawa, D
Hayashi, T
Sakamoto, W
Yamada, M
Hirano, S
机构
[1] Shonan Inst Technol, Dept Mat Sci & Engn, Kanagawa 2518511, Japan
[2] Nagoya Univ, Ctr Integrated Res Sci & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[3] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
D O I
10.1063/1.1560864
中图分类号
O59 [应用物理学];
学科分类号
摘要
Neodymium-doped Bi4Ti3O12 (BNT) films are evaluated for use as lead-free thin-film piezoelectrics in microelectromechanical systems. Bi4Ti3O12, Bi3.25La0.75Ti3O12, and Bi3.25Nd0.75Ti3O12 films were fabricated by chemical solution deposition on Pt/TiOx/SiO2/Si substrates. Nd substitution promoted random orientation with low (00l) diffraction peaks. The 1-mum-thick Bi3.25Nd0.75Ti3O12 film annealed at 750 degreesC exhibited a remanent polarization of 26 muC/cm(2). Typical butterfly field-induced strain loops were obtained in the BNT film capacitors. The electrically induced strain is 8.4x10(-4) under the bipolar driving field of 220 kV/cm. These results show that BNT is a promising candidate for use in lead-free thin-film piezoelectrics. (C) 2003 American Institute of Physics.
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页码:1760 / 1762
页数:3
相关论文
共 16 条
[1]   Spatial variation of ferroelectric properties in Pb(Zr0.3, Ti0.7)O3 thin films studied by atomic force microscopy [J].
Christman, JA ;
Kim, SH ;
Maiwa, H ;
Maria, JP ;
Rodriguez, BJ ;
Kingon, AI ;
Nemanich, RJ .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (11) :8031-8034
[2]   CRYSTAL SYMMETRY OPTICAL PROPERTIES AND FERROELECTRIC POLARIZATION OF BI4TI3O12 SINGLE CRYSTALS [J].
CUMMINS, SE ;
CROSS, LE .
APPLIED PHYSICS LETTERS, 1967, 10 (01) :14-&
[3]   Properties of aluminum nitride thin films for piezoelectric transducers and microwave filter applications [J].
Dubois, MA ;
Muralt, P .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :3032-3034
[4]   Preparation and properties of Bi4-xLaxTi3O12 ferroelectric thin films using excimer UV irradiation [J].
Hayashi, T ;
Togawa, D ;
Yamada, M ;
Sakamoto, W ;
Hirano, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2002, 41 (11B) :6814-6819
[5]  
HAYASHI T, IN PRESS JPN J APPL
[6]   Platinum-assisted phase transition in bismuth-based layer-structured ferroelectric CaBi4Ti4O15 thin films [J].
Kato, K ;
Suzuki, K ;
Fu, DS ;
Nishizawa, K ;
Miki, T .
APPLIED PHYSICS LETTERS, 2002, 81 (17) :3227-3229
[7]   Electromechanical properties of SrBi2Ta2O9 thin films [J].
Kholkin, AL ;
Brooks, KG ;
Setter, N .
APPLIED PHYSICS LETTERS, 1997, 71 (14) :2044-2046
[8]   Interferometric measurements of electric field-induced displacements in piezoelectric thin films [J].
Kholkin, AL ;
Wutchrich, C ;
Taylor, DV ;
Setter, N .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1996, 67 (05) :1935-1941
[9]   Large remanent polarization of (Bi,Nd)4Ti3O12 epitaxial thin films grown by metalorganic chemical vapor deposition [J].
Kojima, T ;
Sakai, T ;
Watanabe, T ;
Funakubo, H ;
Saito, K ;
Osada, M .
APPLIED PHYSICS LETTERS, 2002, 80 (15) :2746-2748
[10]  
MAEDER MD, 2002, PIEZOELECTRIC MAT DE, P389