An octahedral rhodium cluster with six phosphine and 12 hydride Ligands and 10 too few electrons

被引：10

作者：

Dyson, PJ ^{[1
]}

McIndoe, JS

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, BCH, CH-1015 Lausanne, Switzerland

[2] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

cluster compounds; electron counting; hydride ligands; P ligands; rhodium;

D O I：

10.1002/anie.200460924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Six of one and half a dozen of the other: A late-transition-metal octahedral cluster [Rh6(PiPr3)6(μ-H) 12]2+ (1) with six phosphine ligands has been reported with a structure and electron count akin to that of early-transition-metal halide clusters, and provides a unique link between the two classes of cluster (see scheme). Cluster 1 is also decorated with 12 hydride ligands.

引用

页码：6028 / 6030

页数：3

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