The synthesis of specifically metallated heterobimetallic dimeric porphyrins

被引：6

作者：

Belcher, WJ

Burrell, AK

Officer, DL

Reid, DCW

Scott, SM

机构：

[1] Massey Univ, IFS Chem, Nanomat Res Ctr, Palmerston North, New Zealand

[2] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2002年 / 6卷 / 11-12期

关键词：

porphyrins; porphyrin dimers; metallated porphyrin dimers; unsymmetrical porphyrin dimers; porphyrin phosphonium salt; Wittig synthesis;

D O I：

10.1142/S1088424602000841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of conjugated mixed metal heteroporphyrin dimers has been prepared using Wittig chemistry. They can be synthesized from a double Wittig reaction between porphyrin phosphonium salts and phthalaldehydes, or from stepwise Wittig reactions. This allows both symmetrical and unsymmetrical dimers to be prepared with complete control of porphyrin metallation. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.

引用

页码：720 / 736

页数：17

共 27 条

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