ALDEHYDE-APPENDED TETRAPHENYLPORPHYRIN - A NEW BUILDING-BLOCK FOR PORPHYRIN ARRAYS

被引:76
作者
BURRELL, AK [1 ]
OFFICER, DL [1 ]
REID, DCW [1 ]
机构
[1] MASSEY UNIV,DEPT CHEM & BIOCHEM,PALMERSTON NORTH,NEW ZEALAND
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期
关键词
PHOTOSYNTHESIS; PORPHYRINS; PORPHYRINOIDS;
D O I
10.1002/anie.199509001
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porphyrin arrays may act as light‐harvesting devices which mimic the photosynthetic capture of light. Until now the construction of a variety of arrays has been restricted by the lack of suitable methodology for porphyrin synthesis. A fully conjugated, aldehyde‐appended porphyrin building block has been made and its potential demonstrated with the one‐step synthesis of dimers and trimer 1. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码:900 / 902
页数:3
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