Characterization and photoluminescence properties of MgO microtubes synthesized from hydromagnesite flowers

被引：106

作者：

Janet, C. M. ^{[1
]}

Viswanathan, B. ^{[1
]}

Viswanath, R. P. ^{[1
]}

Varadarajan, T. K. ^{[1
]}

机构：

[1] Indian Inst Technol, Natl Ctr Catalysis Res, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2007年 / 111卷 / 28期

关键词：

D O I：

10.1021/jp072539q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Monoclinic hydromagnesite (Mg-5(CO3)(4)center dot(OH)(2)center dot 4H(2)O) flower-like structures of 2-3 mu m diameter have been synthesized at room temperature by a simple precipitation method without using any template, catalyst, or surfactant. The as-synthesized flowers were further calcined at various temperatures to prepare monodispersed, nanofibrous MgO microtubes of aspect ratio similar to 15. Both the precursor flowers and the MgO microtubes formed were characterized by powder XRD, TG-DTA, FT-IR, SEM, EDAX, HR-TEM, SAED, BET analysis and photoluminescence (PL) studies. A plausible mechanism for the formation of cubic MgO microtubes from monoclinic hydromagnesite flowers is proposed. The as-synthesized nanofibrous MgO microtubes have shown intense green and red emission. The more defective MgO microtubes formed in N-2 atmosphere at 400 degrees C showed the highest PL intensity and surface area. An attempt has been made to correlate the lattice parameter and the PL intensity.

引用

页码：10267 / 10272

页数：6

共 48 条

[21] LUMINESCENCE IN THERMOCHEMICALLY REDUCED MGO - THE ROLE OF HYDROGEN [J].

JEFFRIES, BT ;

GONZALEZ, R ;

CHEN, Y ;

SUMMERS, GP .

PHYSICAL REVIEW B, 1982, 25 (03) :2077-2080

[22]

JINHUA Z, 2004, INORG CHEM, V43, P2462

[23]

Kern K., 2003, ANGEW CHEM, V115, P2774, DOI DOI 10.1002/ANGE.200250610

[24]

KEVIN LK, 2002, APPL PHYS LETT, V81, P926

[25]

KOHEI M, 2005, LANGMUIR, V21, P3659

[26] Sol-gel preparation of MgO fibers [J].

Kordas, G .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (05) :1157-1160

[27]

LI YB, 2003, APPL PHYS LETT, V83, P54

[28] Mesoscale organization of CuO nanoribbons: Formation of "dandelions" [J].

Liu, B ;

Zeng, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (26) :8124-8125

[29] A laser ablation method for the synthesis of crystalline semiconductor nanowires [J].

Morales, AM ;

Lieber, CM .

SCIENCE, 1998, 279 (5348) :208-211

[30] Large-scale synthesis of single-crystalline MgO with bone-like nanostructures [J].

Niu, Haixia ;

Yang, Qing ;

Tang, Kaibin ;

Xie, Yi .

JOURNAL OF NANOPARTICLE RESEARCH, 2006, 8 (06) :881-888

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