A Highly Charged Ag64+ Core in a DNA-Encapsulated Silver Nanocluster

被引：61

作者：

Koszinowski, Konrad ^{[1
]}

Ballweg, Korbinian ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 11期

关键词：

cluster compounds; DNA; mass spectrometry; nanoclusters; silver; UV/Vis spectroscopy; AQUEOUS-SOLUTION; METAL-CLUSTERS; MASS-SPECTROMETRY; AG NANOCLUSTERS; REDUCTION; POLYANION; TEMPLATE;

D O I：

10.1002/chem.200902743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly charged; Electrospray-ionization mass spectrometry shows that single-stranded oligonucleotide dC12encapsulated silver nanoclusters contain Ag64+ cores at basic pH values (see section of spectrum). The high positive charge of the cluster cores is presumably essential for preventing the multiply deprotonated dC12 ligand from unfolding. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3285 / 3290

页数：6

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