Rhodium catalyzed hydroformylation of conjugated dienes: Remarkable accelerative effect of triphenylphosphine

被引：31

作者：

Barros, Humberto J. V. ^{[1
]}

Guimaraes, Cristiane C. ^{[1
]}

dos Santos, Eduardo N. ^{[1
]}

Gusevskaya, Elena V. ^{[1
]}

机构：

[1] Univ Fed Minas Gerais, Dept Quim, BR-31270901 Belo Horizonte, MG, Brazil

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 05期

关键词：

hydroformylation; isoprene; myrcene; rhodium catalysts;

D O I：

10.1016/j.catcom.2006.09.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The increase in the concentration of the phosphorous ligand strongly accelerates the rhodium catalyzed hydroformylation of conjugated dienes, that allows to perform the reaction under mild conditions (80-100 degrees C, 40-80 atm) using a low cost and readily accessible ligand: triphenylphosphine (P/Rh = 20-500). (c) 2006 Elsevier B. V. All rights reserved.

引用

页码：747 / 750

页数：4

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