Experimental study on dual recirculation of polymer electrolyte membrane fuel cell

被引:47
作者
Jiang, Hongliang [1 ,2 ]
Xu, Liangfei [1 ,2 ,3 ]
Fang, Chuan [1 ,2 ]
Zhao, Xingwang [1 ,2 ]
Hu, Zunyan [1 ,2 ]
Li, Jianqiu [1 ,2 ]
Ouyang, Minggao [1 ,2 ]
机构
[1] Tsinghua Univ, State Key Lab Automot Safety & Energy, Beijing 100084, Peoples R China
[2] Collaborat Innovat Ctr Elect Vehicles Beijing, Beijing 100081, Peoples R China
[3] Forschungszentrum Julich, Inst Energy & Climate Res, IEK Electrochem Proc Engn 3, D-52425 Julich, Germany
基金
中国国家自然科学基金;
关键词
Polymer electrolyte membrane fuel cell; Anodic recirculation; Cathodic recirculation; Voltage clamping; Self-humidification; Durability; HYDROGEN FLOW; AIR STREAM; DEGRADATION; SYSTEM; DURABILITY;
D O I
10.1016/j.ijhydene.2017.04.183
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
Durability and start-up ability in sub-zero environment are two technical bottlenecks of vehicular polymer electrolyte membrane (PEM) fuel cell systems. With exhaust gas recirculation on the anode and cathode side, the cell voltage at low current density can be reduced, and the membrane can be humidified without external humidifier. They may be helpful to prolong the working lifetime and to promote the start-up ability. This paper presents an experimental study on a PEM fuel cell system with anodic and cathodic recirculation. The system is built up based on a 10 kW fuel cell stack, which consists of 50 cells and has an active area of 261 cm(2). A cathodic recirculation pump and a hydrogen recirculation pump are utilized on the cathode and anode side, respectively. Key parameters, e.g., stack current, stack voltage, cell voltage, air flow, relative humidity on the cathode side, oxygen concentration at the inlet and outlet of the cathode side, are measured. Results show that: 1) with a cathodic recirculation the system gets good self humidification effect, which is similar to that with an external humidifier; 2) with a cathodic recirculation and a reduction of fresh air flux, the cell voltage can be obviously reduced; 3) with an anodic recirculation the cell voltage can also be reduced due to a reduction in the hydrogen partial pressure, the relative humidity on the cathode side is a little smaller than the case with only cathode recirculation. It indicates that, for our stack the cathodic recirculation is effective to clamp cell voltage at low current density, and a self-humidification system is possible with cathodic recirculation. Further study will focus on the dynamic model and control of the dual recirculation fuel cell system. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:18551 / 18559
页数:9
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