Synthetic routes to N-heterocyclic carbene complexes: Pyridine-carbene tautomerizations

被引：51

作者：

Kunz, Doris ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 19期

关键词：

1,2 H-shift; C-H activation; carbenes; pyridines; tautomerization;

D O I：

10.1002/anie.200700192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) 70 years ago the existence of the 2-carbene isomer of pyridine, which arises by pyridine-carbene tautomerization (see scheme), was postulated. Now it has been prepared from pyridine as a stable carbene complex by metal-induced C-H activation. This pyridine-carbene tautomerization is described and discussed along with other analogous carbene tautomerization reactions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3405 / 3408

页数：4

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