Molecular symmetry breaking and chiral expression of discotic liquid crystals in two-dimensional systems

被引：30

作者：

Li, CJ ^{[1
]}

Zeng, QD ^{[1
]}

Wu, P ^{[1
]}

Xu, SL ^{[1
]}

Wang, C ^{[1
]}

Qiao, YH ^{[1
]}

Wan, LJ ^{[1
]}

Bai, CL ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 51期

关键词：

D O I：

10.1021/jp020376u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have studied the self-assembled monolayers from a series of discotic liquid crystal molecules on graphite substrate using scanning tunneling microscopy. An emergence of chirality in 1,7,13-trialkanoyldecacyclene (with n-carbon side chains, n=14) monolayers was observed in the assembly. The driving force of the assembling behavior could be related to a cooperative interaction mechanism, possibly due to intermolecular steric hindrance, two-dimensional crystallization of alkyl substitutents.

引用

页码：13262 / 13267

页数：6

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