Stereoselective syntheses of 4-amino-aldoses, and chiral pyrrolidine derivatives from glycosylenamines

被引:11
作者
Fuentes, J
Olano, D
Pradera, MA
机构
[1] Dpto. de Quim. Orgánica, Facultad de Química, Universidad de Sevilla, E-41071 Sevilla
关键词
D O I
10.1016/S0957-4166(97)00404-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The stereocontrolled synthesis of N-protected 4-amino-4-deoxy-D-galacto- and -L-arabino-pyranoses starting from glycosylenamines via aza-anhydropyranoses is described. The steroselective transformation of the intermediate aza-anhydropyranoses into chiral pyrrolidines is also reported. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3443 / 3456
页数:14
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[41]   A MILD PROCEDURE FOR CLEAVAGE OF 1,6-ANHYDRO SUGARS [J].
ZOTTOLA, M ;
RAO, BV ;
FRASERREID, B .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) :969-970