Trimethoxyboroxine as an 'oxygen-transfer' reagent: a non-aqueous 'sol-gel' route to alkali-free borosilicate glass

被引：18

作者：

Beckett, MA ^{[1
]}

Rugen-Hankey, MP

Varma, KS

机构：

[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

[2] European Tech Ctr, Pilkington Grp Res, Lathom L40 5UF, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b003047n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthesis of alkali-free borosilicate gel from Si(OEt)(4) and (MeO)(3)B3O3 in non-aqueous solvents is reported; the formation of the gel proceeds via rapid transesterification/oxygen transfer with elimination of B(OR)(3); removal of volatiles from the gel, followed by drying (60 degrees C, 12 h) and furnacing in air (600 degrees C, 20 min) resulted in alkali-free borosilicate glass.

引用

页码：1499 / 1500

页数：2

共 19 条

[11]

Kasgöz A, 1999, J NON-CRYST SOLIDS, V243, P168, DOI 10.1016/S0022-3093(98)00821-7

[12] Preparation and Microstructure Study of Borosilicate Coatings Produced by Sol-Gel [J].

Pellegri, N. ;

de Sanctis, O. ;

Duran, A. .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) :519-523

[13] TRANSESTERIFICATION REACTIONS OF ALKYL SILICATES [J].

PEPPARD, DF ;

BROWN, WG ;

JOHNSON, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (01) :77-79

[14] NMR-STUDY OF THE SOL-GEL POLYMERIZATION [J].

POUXVIEL, JC ;

BOILOT, JP ;

BELOEIL, JC ;

LALLEMAND, JY .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 89 (03) :345-360

[15] VIBRATIONAL-SPECTRA OF VAPOR-DEPOSITED BINARY BOROSILICATE GLASSES [J].

TENNEY, AS ;

WONG, J .

JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (11) :5516-+

[16]

TOHGE N, 1987, J AM CERAM SOC, V70, pC13, DOI 10.1111/j.1151-2916.1987.tb04860.x

[17]

VARMA KS, 1998, Patent No. 42627

[18] Preparation and spectroscopy of anhydrous borosilicate sols and their application to thin films [J].

Zha, CJ ;

Atkins, GR ;

Masters, AF .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 242 (01) :63-67

[19] A spectroscopic study of an anhydrous tetraethyl orthosilicate boric acid ethanol system [J].

Zha, CJ ;

Atkins, GR ;

Masters, AF .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 13 (1-3) :103-107

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