Constructing Carbon Nanotube/Pt Nanoparticle Hybrids Using an Imidazolium-Salt-Based Ionic Liquid as a Linker

被引:241
作者
Guo, Shaojun [1 ,2 ]
Dong, Shaojun [1 ,2 ]
Wang, Erkang [1 ,2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
METHANOL FUEL-CELLS; OXYGEN REDUCTION; ELECTROCHEMICAL DEVICES; GOLD NANOPARTICLES; AU NANOPARTICLES; METAL; FUNCTIONALIZATION; NANOFIBERS; TEMPLATES; OXIDATION;
D O I
10.1002/adma.200903379
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon nanotube (CNT)/Pt nanoparticle (NP) hybrids are synthesized at room temperature using an imidazolium-salt-based ionic liquid (IS-ILs) as a linker. The new three-component CNT/IS-ILs/metal heterostructure has uniformly distributed Pt NPs, which form a conducting network on the CNTs that leads to high electrocatalytic activity. The hybrid is shown to exhibit higher electrocatalytic activity towards methanol oxidation reactions than a commercial hybrid catalyst and a hybrid containing polymeric linkers.
引用
收藏
页码:1269 / +
页数:5
相关论文
共 27 条
[1]   Decorating carbon nanotubes with metal or semiconductor nanoparticles [J].
Georgakilas, Vasilios ;
Gournis, Dimitrios ;
Tzitzios, Vasilios ;
Pasquato, Lucia ;
Guldi, Dirk M. ;
Prato, Maurizio .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (26) :2679-2694
[2]   Constructing carbon-nanotube/metal hybrid nanostructures using homogeneous TiO2 as a spacer [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
SMALL, 2008, 4 (08) :1133-1138
[3]   Gold/platinum hybrid nanoparticles supported on multiwalled carbon nanotube/silica coaxial nanocables: Preparation and application as electrocatalysts for oxygen reduction [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (07) :2389-2393
[4]   Polyaniline/Pt Hybrid Nanofibers: High-Efficiency Nanoelectrocatalysts for Electrochemical Devices [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
SMALL, 2009, 5 (16) :1869-1876
[5]   Carbon Nanotube/Silica Coaxial Nanocable as a Three-Dimensional Support for Loading Diverse Ultra-High-Density Metal Nanostructures: Facile Preparation and Use as Enhanced Materials for Electrochemical Devices and SERS [J].
Guo, Shaojun ;
Li, Jing ;
Ren, Wen ;
Wen, Dan ;
Dong, Shaojun ;
Wang, Erkang .
CHEMISTRY OF MATERIALS, 2009, 21 (11) :2247-2257
[6]   DNA-wrapped single-walled carbon nanotubes as rigid templates for assembling linear gold nanoparticle arrays [J].
Han, Xiaogang ;
Li, Yulin ;
Deng, Zhaoxiang .
ADVANCED MATERIALS, 2007, 19 (11) :1518-+
[7]   Poly(vinylpyrrolidone)-modified graphite carbon nanofibers as promising supports for PtRu catalysts in direct methanol fuel cells [J].
Hsin, Yu Lin ;
Hwang, Kuo Chu ;
Yeh, Chuin-Tih .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (32) :9999-10010
[8]   Carbon nanotube/gold nanoparticles/polyethylenimine-functionalized ionic liquid thin film composites for glucose biosensing [J].
Jia, Fei ;
Shan, Changsheng ;
Li, Fenghua ;
Niu, Li .
BIOSENSORS & BIOELECTRONICS, 2008, 24 (04) :945-950
[9]   Modified carbon nanotubes: an effective way to selective attachment of gold nanoparticles [J].
Jiang, LQ ;
Gao, L .
CARBON, 2003, 41 (15) :2923-2929
[10]   Chemically induced potential barriers at the carbon nanotube-metal nanoparticle interface [J].
Kauffman, Douglas R. ;
Star, Alexander .
NANO LETTERS, 2007, 7 (07) :1863-1868