Chlorine abstraction by laser pyrolysis of W(CO)6;: a mild route to gas-phase organic radical chemistry

被引：5

作者：

Allen, GR ^{[1
]}

Renner, ND ^{[1
]}

Russell, DK ^{[1
]}

机构：

[1] Univ Auckland, Dept Chem, Auckland, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a708737c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SF6-photosensitised IR laser pyrolysis of W(CO)(6) in the gas phase at moderate temperatures leads to unsaturated W(CO)(n) species; these prove to be very effective and selective abstractors of Cl atoms from a wide range of organic substrates, and offer a low energy and clean route into gas phase organic radical chemistry.

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页码：703 / 704

页数：2

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