The first structurally alternating copper(II) chain with alternate single end-on and end-to-end azido bridging: A synthesis, crystal structure, and low-temperature magnetic study

被引：107

作者：

Mukherjee, PS

Maji, TK

Mostafa, G

Mallah, T

Chaudhuri, NR ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

[2] Krishnath Coll, Dept Phys, Berhampur 742109, Orissa, India

[3] Univ Paris 11, CNRS, URA 420, Chim Inorgan Lab, F-91405 Orsay, France

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 22期

关键词：

D O I：

10.1021/ic000507a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 1-D chain of Cu(II) with alternate single end-on and single end-to-end azido bridge having a very high Cu - N3(1,1) - Cu bond angle (129.98°) has been synthesized and characterized, which shows an intra-chain antiferronmagnetic interaction (J = -11.5 cm-1 for end-on bridge and -2.7 cm-1 for end-to-end bridge).

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页码：5147 / 5150

页数：4

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