Tuning the Spin States of Two Apical Iron(II) Ions in the Trigonal-Bipyramidal [{FeII(μ-bpt)3}2FeII3(μ3-O)]2+ Cations Through the Choice of Anions

被引：55

作者：

Bao, Xin ^{[1
]}

Leng, Ji-Dong ^{[1
]}

Meng, Zhao-Sha ^{[1
]}

Lin, Zhuojia ^{[1
]}

Tong, Ming-Liang ^{[1
]}

Nihei, Masayuki ^{[2
]}

Oshio, Hiroki ^{[2
]}

机构：

[1] Sun Yat Sen Univ, Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol,Minist Educ, Guangzhou 510275, Guangdong, Peoples R China

[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 21期

关键词：

cluster compounds; iron; magnetic properties; spin transitions; triazoles; LADDER-TYPE COMPOUNDS; MAGNETIC-PROPERTIES; PHOTOMAGNETIC PROPERTIES; METALORGANIC FRAMEWORKS; CROSSOVER COMPLEXES; LANTHANIDE ELEMENT; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; SINGLE-CRYSTAL; LIGHT;

D O I：

10.1002/chem.201000526

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Polinuclear Fe II Clusters: A new family of {Fe 5} cluster compounds formulated with [{Fe II(μ-bpt) 3} 2Fe 3 II(μ3O)]X 2 have been synthesised from the solvothermal reactions of 4-amino-3,5-bis(pyridine-2- yl)-1,2,4-triazole with-ferrous salts. The spin states of the two apical iron(II) ions in the cationic pentanuclear (Fe 5} clusters can be tuned to give the high-spin states by the [Fe 2OCl 6] 2- anion and the low-spin states by SCN -/ClO 4 -/I - (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：6169 / 6174

页数：6

相关论文

共 73 条

[31] THE (MU-OXO)BIS[TRICHLOROFERRATE(III)] DIANION REVISITED [J].

HASELHORST, G ;

WIEGHARDT, K ;

KELLER, S ;

SCHRADER, B .

INORGANIC CHEMISTRY, 1993, 32 (05) :520-525

[32] Novel structural and magnetic properties of a 1-D iron(II)-manganese(II) LIESST compound bridged by cyanide [J].

Hayami, S ;

Juhász, G ;

Maeda, Y ;

Yokoyama, T ;

Sato, O .

INORGANIC CHEMISTRY, 2005, 44 (21) :7289-7291

[33] Structural studies and magnetic properties of polymeric ladder-type compounds {Ln2[Ni(opba)]3}•S (Ln = lanthanide element; opba = o-phenylenebis(oxamato), S = solvent molecules) [J].

Kahn, ML ;

Lecante, P ;

Verelst, M ;

Mathonière, C ;

Kahn, O .

CHEMISTRY OF MATERIALS, 2000, 12 (10) :3073-3079

[34] Nature of the interaction between LnIII and CuII ions in the ladder-type compounds {Ln2[Cu(opba)]3}•S (Ln = lanthanide element; opba = ortho-phenylenebis(oxamato), S = solvent molecules) [J].

Kahn, ML ;

Mathonière, C ;

Kahn, O .

INORGANIC CHEMISTRY, 1999, 38 (16) :3692-3697

[35] Spin-transition polymers: From molecular materials toward memory devices [J].

Kahn, O ;

Martinez, CJ .

SCIENCE, 1998, 279 (5347) :44-48

[36]

Kahn O., 1993, MOL MAGNETISM

[37] Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates [J].

Kitchen, Jonathan A. ;

Brooker, Sally .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (18-20) :2072-2092

[38] Iron(II) Tris-[N4-substituted-3,5-di(2-pyridyl)-1,2,4-triazole] Complexes: Structural, Magnetic, NMR, and Density Functional Theory Studies [J].

Kitchen, Jonathan A. ;

White, Nicholas G. ;

Boyd, Maruta ;

Moubaraki, Boujemaa ;

Murray, Keith S. ;

Boyd, Peter D. W. ;

Brooker, Sally .

INORGANIC CHEMISTRY, 2009, 48 (14) :6670-6679

[39] Coordination algorithms control molecular architecture:: [CuI4(L2)4]4+ grid complex versus [MII2(L2)2X4]y+ side-by-side complexes (M = Mn, Co, Ni, Zn; X = solvent or anion) and [FeII(L2)3][Cl3FeIIIOFeIIICl3] [J].

Lan, YH ;

Kennepohl, DK ;

Moubaraki, B ;

Murray, KS ;

Cashion, JD ;

Jameson, GB ;

Brooker, S .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (16) :3772-3784

[40] Light induced excited pair spin state in an iron(II) binuclear spin-crossover compound [J].

Létard, JF ;

Real, JA ;

Moliner, N ;

Gaspar, AB ;

Capes, L ;

Cador, O ;

Kahn, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (45) :10630-10631

← 1 2 3 4 5 6 7 8 →