Selection of a representative matrix for calibration in multianalyte determination of pesticides in vegetables by liquid chromatography-electrospray tandem mass spectrometry

被引：21

作者：

Vidal, JLM ^{[1
]}

Frenich, AG

López, TL

Salvador, IM

el Hassani, LH

Benajiba, MH

机构：

[1] Univ Almeria, Dept Analyt Chem, Almeria 04071, Spain

[2] CUAM, Lab Pesticide Residues, El Ejido 04700, Almeria, Spain

[3] Univ Abdelmalek Essaadi, Dept Biol, Tetouan 93002, Morocco

来源：

CHROMATOGRAPHIA | 2005年 / 61卷 / 3-4期

关键词：

column liquid chromatography-mass spectrometry; matrix effects; pesticide residues in vegetables;

D O I：

10.1365/s10337-004-0488-1

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An analytical method for determining residues of twenty pesticides by liquid chromatography (LC) coupled to electrospray ionisation (ESI) tandem mass spectrometry (MS-MS) in eight commodities, cucumber, tomato, pepper, green bean, eggplant, zucchini, melon and water-melon, has been developed and validated. On one hand, calibration curves prepared in solvent were compared with calibration curves prepared in a blank matrix extract of each target matrix. On the other hand, calibration curves and recoveries for each commodity were compared. Cucumber was selected as potential reference matrix for the target vegetables.

引用

页码：127 / 131

页数：5