New cluster condensation modes in early transition metal thiophosphates:: synthesis, structure and properties of CsTa4P3S19, a novel layered material

被引：21

作者：

Derstroff, V ^{[1
]}

Tremel, W ^{[1
]}

机构：

[1] Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a801155i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new layer compound CsTa4S5(S-2)(PS4)(3) was synthesized by the reaction of Ta metal in polythiophosphate melts. Its structure is based on Ta4S5(S-2) clusters which are condensed by PS43- groups.

引用

页码：913 / 914

页数：2

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