Electrochemical instability of LiV3O8 as an electrode material for aqueous rechargeable lithium batteries

被引：83

作者：

Caballero, A. ^{[1
]}

Morales, J. ^{[1
]}

Vargas, O. A. ^{[1
]}

机构：

[1] Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain

来源：

JOURNAL OF POWER SOURCES | 2010年 / 195卷 / 13期

关键词：

Vanadium oxide; Lithium cells; Aqueous batteries; GOOD CYCLING PERFORMANCE; HIGH-POWER; ION CELLS; BEHAVIOR; LIMN2O4; ANODE; ARLB;

D O I：

10.1016/j.jpowsour.2010.01.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

We demonstrate the unsuitability of LiV3O8 as an electrode material for aqueous rechargeable lithium batteries on simple but solid grounds: the compound is unstable under typical battery operation conditions, where it slowly dissolves as reflected in the yellow color acquired by the electrolyte. This can be the origin of the poor performance of the aqueous batteries based on this compound. (C) 2010 Elsevier B.V. All rights reserved.

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页码：4318 / 4321

页数：4

相关论文

共 21 条

[1]

Improved lithium manganese oxide spinel/graphite Li-ion cells for high-power applications [J].

Amine, K ;

Liu, J ;

Kang, S ;

Belharouak, I ;

Hyung, Y ;

Vissers, D ;

Henriksen, G .

JOURNAL OF POWER SOURCES, 2004, 129 (01) :14-19

[2]

Nanostructured materials for advanced energy conversion and storage devices [J].

Aricò, AS ;

Bruce, P ;

Scrosati, B ;

Tarascon, JM ;

Van Schalkwijk, W .

NATURE MATERIALS, 2005, 4 (05) :366-377

[3]

Crystallinity control of a nanostructured LiNi0.5Mn1.5O4 spinet via polymer-assisted synthesis:: A method for improving its rate capability and performance in 5 V lithium batteries [J].

Arrebola, Jose C. ;

Caballero, Alvaro ;

Cruz, Manuel ;

Hernan, Lourdes ;

Morales, Julian ;

Castellon, Enrique Rodriguez .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (14) :1904-1912

[4]

Electrochemical behavior of thin-film LiMn2O4 electrode in aqueous media [J].

Eftekhari, A .

ELECTROCHIMICA ACTA, 2001, 47 (03) :495-499

[5]

LiV3O8:: characterization as anode material for an aqueous rechargeable Li-ion battery system [J].

Köhler, J ;

Makihara, H ;

Uegaito, H ;

Inoue, H ;

Toki, M .

ELECTROCHIMICA ACTA, 2000, 46 (01) :59-65

[6]

Rate capabilities of nanostructured LiMn2O4 electrodes in aqueous electrolyte [J].

Li, NC ;

Patrissi, CJ ;

Che, GL ;

Martin, CR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (06) :2044-2049

[7]

LITHIUM-ION CELLS WITH AQUEOUS-ELECTROLYTES [J].

LI, W ;

DAHN, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :1742-1746

[8]

LITHIUM INTERCALATION FROM AQUEOUS-SOLUTIONS [J].

LI, W ;

MCKINNON, WR ;

DAHN, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (09) :2310-2316

[9]

RECHARGEABLE LITHIUM BATTERIES WITH AQUEOUS-ELECTROLYTES [J].

LI, W ;

DAHN, JR ;

WAINWRIGHT, DS .

SCIENCE, 1994, 264 (5162) :1115-1118

[10]

Aqueous lithium-ion battery LiTi2(PO4)3/LiMn2O4 with high power and energy densities as well as superior cycling stability [J].

Luo, Jia-Yan ;

Xia, Yong-Yao .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3877-3884