Gold(I) complex of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) as a metalloligand for encapsulation of metal ions.: Crystal structures of [AuCu(dpnapy)3][ClO4]2 and [AuCd(dpnapy)3][ClO4]3

被引：18

作者：

Chan, WH

Cheung, KK

Mak, TCW

Che, CM

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Hong Kong

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a800061a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of dpnapy [dpnapy = 7-diphenylphosphino-2,4-dimethyl- 1,8-naphthyridine] with [Au(tht)Cl] (tht = tetrahydrothiophene) in dichloromethane afforded [Au(dpnapy)(3)](+), which shows a strong affinity towards Cu-I and Cd-II ions; crystal structures of [AuCu(dpnapy)(3)][ClO4](2) and [AuCd(dpnapy)(3)][ClO4](3) revealed that [Au(dpnapy)(3)](+) functions as a metalloligand with the three naphthyridyl groups positioned in a trigonal fashion.

引用

页码：873 / 874

页数：2

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