Synthesis of new bicyclic P-N ligands and their application in asymmetric Pd-catalyzed π-allyl alkylation and Heck reaction

被引：81

作者：

Gilbertson, SR

Genov, DG

Rheingold, AL

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63170 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 18期

关键词：

D O I：

10.1021/ol006323h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of phosphine oxazoline ligands based on P-chiral 1-phosphanorbornadienes is reported. The use of these ligands in palladium catalyzed asymmetric allylation and Heck reaction is described.

引用

页码：2885 / 2888

页数：4

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