Block copolymers build-up of electron and hole transport materials

被引：24

作者：

Behl, M ^{[1
]}

Zentel, R ^{[1
]}

机构：

[1] Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2004年 / 205卷 / 12期

关键词：

block copolymers; living polymerization; radical polymerization; triazines; triphenylamines;

D O I：

10.1002/macp.200400110

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this article we describe the synthesis of various monomers modified with triphenyl-1,3,5-triazine side groups as electron transport moieties. By nitroxide-mediated polymerization with a TEMPO unimer it was possible to obtain polymers with a narrow polydispersity. Furthermore, by living radical polymerization block copolymers were obtained from these monomers. Therefore, microphase separated structures are accessible which possess hole conducting moieties in one phase and electron conducting moieties in the other phase.

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页码：1633 / 1643

页数：11

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