γ-radiation sensor using optical and electrical properties of manganese phthalocyanine (MnPc) thick film

被引:41
作者
Arshak, A [1 ]
Zleetni, S [1 ]
Arshak, K [1 ]
机构
[1] Univ Limerick, Dept Elect & Comp Engn, Limerick, Ireland
来源
SENSORS | 2002年 / 2卷 / 05期
关键词
optical band gap; gamma-rays; dosimetry; manganese phthalocyanine; MnPc;
D O I
10.3390/s20500174
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Manganese phthaloyanine polymer thick films were fabricated using screen-printing techniques. The optical parameters were obtained from the analysis of the absorption spectra over a wavelength range of 385-900nm. The d. c. electrical measurements were carried out in a range of 0-30 volts. The effects of gamma-radiation on the optical and the electrical properties were investigated for dosimetry applications. The optical energy band gaps of these films showed a decrease in their values with the increase in the radiation dose. The electronic transition has changed from direct allowed for the as-printed films (unexposed to gamma-rays) to indirect allowed for the irradiated samples. Both the as-printed and irradiated Ag/MnPc/Ag devices demonstrated a Schottky conduction mechanism. Both the absorbance and the capacitance of the MnPc thick films displayed a highly consistent linear response to gamma-ray exposure.
引用
收藏
页码:174 / 184
页数:11
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