Dye-sensitized solar cells using TiO2 nanoparticles transformed from nanotube arrays

被引:28
作者
Alivov, Yahya [1 ,2 ]
Fan, Z. Y. [1 ,2 ]
机构
[1] Texas Tech Univ, Dept Elect & Comp Engn, Lubbock, TX 79409 USA
[2] Texas Tech Univ, Nano Tech Ctr, Lubbock, TX 79409 USA
关键词
ANODIC GROWTH; CONVERSION;
D O I
10.1007/s10853-010-4281-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Dye-sensitized solar cells (DSSCs) were fabricated using TiO2 mesoporous layers obtained by very simple method-transformation of TiO2 nanotube (NT) films grown by electrochemical oxidation to nanoparticle (NP) films. This transformation is based on thermal annealing of TiO2 NT arrays formed by anodization of titanium foil in fluorine ambient. Performance of DSSCs fabricated with different size NPs was studied in the range from 35 to 350 nm. Highest nominal efficiency (9.05%) was achieved for DSSC with NP size 65 nm while the lowest nominal efficiency (1.48%) was observed for DSSCs with NP size 350 nm. The dependence of the solar cell parameters with NP size is discussed.
引用
收藏
页码:2902 / 2906
页数:5
相关论文
共 15 条
[1]   A TiO2 nanostructure transformation: from ordered nanotubes to nanoparticles [J].
Alivov, Yahya ;
Fan, Z. Y. .
NANOTECHNOLOGY, 2009, 20 (40)
[2]   The anodization voltage influence on the properties of TiO2 nanotubes grown by electrochemical oxidation [J].
Alivov, Yahya ;
Pandikunta, Mahesh ;
Nikishin, Sergey ;
Fan, Z. Y. .
NANOTECHNOLOGY, 2009, 20 (22)
[3]   A Method for Fabrication of Pyramid-Shaped TiO2 Nanoparticles with a High {001} Facet Percentage [J].
Alivov, Yahya ;
Fan, Z. Y. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (30) :12954-12957
[4]   Physical chemical principles of photovoltaic conversion with nanoparticulate, mesoporous dye-sensitized solar cells [J].
Bisquert, J ;
Cahen, D ;
Hodes, G ;
Rühle, S ;
Zaban, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8106-8118
[5]   Solar energy conversion by dye-sensitized photovoltaic cells [J].
Grätzel, M .
INORGANIC CHEMISTRY, 2005, 44 (20) :6841-6851
[6]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[7]   Interfacial recombination processes in dye-sensitized solar cells and methods to passivate the interfaces [J].
Gregg, BA ;
Pichot, F ;
Ferrere, S ;
Fields, CL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (07) :1422-1429
[8]   A novel hybrid nanocrystalline TiO2 electrode for the dye-sensitized nanocrystalline solar cells [J].
Han, HW ;
Zan, L ;
Zhong, JS ;
Zhao, XZ .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (18) :4921-4923
[9]   Dye-sensitized core-shell nanocrystals:: Improved efficiency of mesoporous tin oxide electrodes coated with a thin layer of an insulating oxide [J].
Kay, A ;
Grätzel, M .
CHEMISTRY OF MATERIALS, 2002, 14 (07) :2930-2935
[10]   Anodic growth of self-organized anodic TiO2 nanotubes in viscous electrolytes [J].
Macak, Jan M. ;
Schmuki, Patrik .
ELECTROCHIMICA ACTA, 2006, 52 (03) :1258-1264