Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes

被引：16

作者：

Anderson, JC ^{[1
]}

Flaherty, A ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 18期

关键词：

D O I：

10.1039/b006049f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mild and high yielding protodesilylation of C-2 trialkylsilyl terminal alkenes can be effected via a hydroboration-Peterson elimination protocol or, in the case of the phenyldimethylsilyl analogues, a one pot procedure using t-BuOK-18-C-6-TBAF can be used.

引用

页码：3025 / 3027

页数：3

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