Phenol and organic bases co-catalyzed chemical fixation of carbon dioxide with terminal epoxides to form cyclic carbonates

被引：188

作者：

Shen, YM

Duan, WL

Shi, M

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

[2] E China Univ Sci & Technol, Shanghai 200237, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 03期

关键词：

chemical fixation of carbon dioxide; epoxide; green chemistry; organic base; phenol;

D O I：

10.1002/adsc.200390035

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Phenol can efficiently catalyze the reactions of terminal epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases such as 4-dimethylaminopyridine (DMAP), pyridine, 1,8-diazabicyclo[5.4.0]undec-7-ene, and triethylamine to give the corresponding five-membered cyclic carbonate in high yields (initial pressure 3.57 MPa; reaction temperature 120 degreesC). p-Methoxyphenol with DMAP is the best combination to give the cyclic carbonate in the highest yield.

引用

收藏

页码：337 / 340

页数：4

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