Novel heteroleptic cis-(C N)2Pd(II) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

被引：30

作者：

Berger, A

Djukic, JP

Pfeffer, M

de Cian, A

Kyritsakas-Gruber, N

Lacour, J

Vial, L

机构：

[1] CNRS, UMR 7513, Lab Synth Met Induites, F-67070 Strasbourg, France

[2] CNRS, UMR 7513, Serv Commun Anal Diffract Rayons X, F-67070 Strasbourg, France

[3] Univ Geneva, Dept Chim Organ, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 05期

关键词：

D O I：

10.1039/b211873d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(eta(6)-phenyl) tricarbonylchromium] pyridine with mu-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C<^>N)(2)Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (eta(6)-are-ne) Cr(CO)(3) complexes.

引用

页码：658 / 659

页数：2

共 16 条

[1] Metalated (η6-arene)tricarbonylchromium complexes in organometallic chemistry
Berger, A
Djukic, JP
Michon, C
[J]. COORDINATION CHEMISTRY REVIEWS, 2002, 225 (1-2) : 215 - 238
[2] Syntheses of ortho-mercurated and -palladated (η6-arene)tricarbonylchromium complexes
Berger, A
de Cian, A
Djukic, JP
Fischer, J
Pfeffer, M
[J]. ORGANOMETALLICS, 2001, 20 (15) : 3230 - 3240
[3] ELECTROPHILIC AROMATIC SUBSTITUTION REACTIONS BY PLATINUM(2) AND PALLADIUM(2) CHLORIDES ON N,N-DIMETHYLBENZYLAMINES
COPE, AC
FRIEDRICH, EC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (04) : 909 - +
[4] DEUTSCHELCORNIO.C, 1990, J CHEM SOC CHEM COMM, P121
[5] Chiral cyclometalated platinum(II) and palladium(II) complexes with derivatives of thienylpyridine as ligands: Helical distortion of the square planar (SP-4) geometry
Gianini, M
von Zelewsky, A
Stoeckli-Evans, H
[J]. INORGANIC CHEMISTRY, 1997, 36 (26) : 6094 - 6098
[6] VIBRATIONAL SPECTROSCOPIC STUDIES OF TETRA-NORMAL-BUTYLAMMONIUM TRIHALOGENOMERCURATES - CRYSTAL-STRUCTURES OF [NBU-NORMAL-4](HGCL3) AND [NBU-NORMAL-4]-(HGL3)
GOGGIN, PL
KING, P
MCEWAN, DM
TAYLOR, GE
WOODWARD, P
SANDSTROM, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (05): : 875 - 882
[7] Cyclometalated complexes of palladium(II) and platinum(II): cis-Configured homoleptic and heteroleptic compounds with aromatic C-N ligands
Jolliet, P
Gianini, M
vonZelewsky, A
Bernardinelli, G
StoeckliEvans, H
[J]. INORGANIC CHEMISTRY, 1996, 35 (17) : 4883 - 4888
[8] Application of TRISPHAT anion as NMR chiral shift reagent
Lacour, J
Ginglinger, C
Favarger, F
TorcheHaldimann, S
[J]. CHEMICAL COMMUNICATIONS, 1997, (23) : 2285 - 2286
[9] Synthesis and resolution of the configurationally stable tris(tetrachlorobenzenediolato)phosphate(V) ion
Lacour, J
Ginglinger, C
Grivet, C
Bernardinelli, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06): : 608 - 610
[10] ORGANOPALLADIUM COMPOUNDS WITH A CHIRAL PALLADATED CARBON-ATOM - FACILE ISOLATION OF OPTICALLY-ACTIVE CYCLOPALLADATED COMPLEXES CONTAINING THE (S)-[2-NMEZC6H4CH(SIME3)] OR (R)-[2-NME2C6H4CH(SIME3)] MONOANION .1. MOLECULAR-STRUCTURE OF (2-[1-(S)-(DIMETHYLAMINO)ETHYL]PHENYL)[2-(DIMETHYLAMINO)-ALPHA-(TRIMETHYLSILYL)BENZYL]PALLADIUM(II)M
MAASSARANI, F
PFEFFER, M
LEBORGNE, G
JASTRZEBSKI, JTBH
VANKOTEN, G
[J]. ORGANOMETALLICS, 1987, 6 (05) : 1111 - 1118

← 1 2 →