Novel heteroleptic cis-(C N)2Pd(II) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

被引：30

作者：

Berger, A

Djukic, JP

Pfeffer, M

de Cian, A

Kyritsakas-Gruber, N

Lacour, J

Vial, L

机构：

[1] CNRS, UMR 7513, Lab Synth Met Induites, F-67070 Strasbourg, France

[2] CNRS, UMR 7513, Serv Commun Anal Diffract Rayons X, F-67070 Strasbourg, France

[3] Univ Geneva, Dept Chim Organ, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 05期

关键词：

D O I：

10.1039/b211873d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(eta(6)-phenyl) tricarbonylchromium] pyridine with mu-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C<^>N)(2)Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (eta(6)-are-ne) Cr(CO)(3) complexes.

引用

页码：658 / 659

页数：2

共 16 条

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