Hydrogen-protected acenes

被引：24

作者：

Athans, Andreas J. ^{[1
]}

Briggs, Jonathan B. ^{[1
]}

Jia, Wenling ^{[1
]}

Miller, Glen P. ^{[1
]}

机构：

[1] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2007年 / 17卷 / 25期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/b700956a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first systematic study concerning the hydrogenation of acenes and acene quinones is presented. Phenyl substituted acenes and acene quinones are hydrogenated in excellent yield and with complete regioselectivity using HI-AcOH. The resulting H-protected acenes bear alternating aromatic and non-aromatic rings and are stable, soluble molecules that may be stored indefinitely and then deprotected to afford the parent acenes. In this manner, H-protected acenes have been utilized in the syntheses of several [60] fullerene-acene adducts. Buckminsterfullerene also hydrogenates in HI-AcOH yielding C-3 nu symmetric C60H18.

引用

页码：2636 / 2641

页数：6

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