Facile, scalable, regioselective synthesis of C3v C60H18 using organic polyamines

被引：22

作者：

Briggs, JB

Montgomery, M

Silva, LL

Miller, GP ^{[1
]}

机构：

[1] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA

[2] Univ New Hampshire, Mat Sci Program, Durham, NH 03824 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 25期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ol0519339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organic polyamines are efficient reagents for the regioselective hydrogenation of [60]fullerene. When [60]fullerene is heated in diethylenetriamine, a known C60H18 isomer with C-3v symmetry is produced and isolated in good purity without the need for chromatographic separation. The reaction can be scaled upward to multigram levels without impacting yield or quality of product.

引用

收藏

页码：5553 / 5555

页数：3

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