BIRCH REDUCTION OF C(60) - A NEW APPRAISAL

被引：51

作者：

BANKS, MR

DALE, MJ

GOSNEY, I

HODGSON, PKG

JENNINGS, RCK

JONES, AC

LECOULTRE, J

LANGRIDGESMITH, PRR

MAIER, JP

SCRIVENS, JH

SMITH, MJC

SMYTH, CJ

TAYLOR, AT

THORBURN, P

WEBSTER, AS

机构：

[1] BP INT LTD,SUNBURY RES CTR,SUNBURY TW16 7LN,MIDDX,ENGLAND

[2] ICI PLC,WILTON MAT RES CTR,MIDDLESBROUGH TS6 8JE,CLEVELAND,ENGLAND

[3] UNIV BASEL,INST PHYS CHEM,CH-4056 BASEL,SWITZERLAND

[4] UNIV EDINBURGH,DEPT MATH & STAT,EDINBURGH EH8 9JZ,MIDLOTHIAN,SCOTLAND

[5] ROYAL OBSERV,EDINBURGH EH9 3HJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Contrary to a previous report that Birch reduction of C60 affords C60H36 as the principal product, laser desorption-laser photoionisation time-of-flight (L2TOF), laser desorption Fourier transform ion cyclotron resonance (FTICR), and liquid secondary ion mass spectrometry (LSIMS) show collectively that a mixture of polyhydrofullerenes, containing C60H18 through to C60H36 with a skewed distribution centred on C60H32 is formed, the discrepancy in results arising from the thermal lability of this mixture of polyhydrofullerenes when subjected to the elevated temperatures (>250-degrees-C) required for mass spectroscopic studies using direct-insertion heated probes.

引用

页码：1149 / 1152

页数：4

共 14 条

[1] HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC SEPARATION OF FULLERENE MIXTURES USING A NOVEL STATIONARY-PHASE [J].