STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF THE PRODUCTS OF THE C-60-PIPERAZINE REACTION

被引：31

作者：

BALCH, AL

CULLISON, B

FAWCETT, WR

GINWALLA, AS

OLMSTEAD, MM

WINKLER, K

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 22期

关键词：

D O I：

10.1039/C39950002287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal structures of C60N2(C2H4)(2) and C-60{N-2(C2H4)(2)}(2) show that addition occurs with elongation of the C-C bond at the 6:6 ring junction to which the two nitrogen atoms are bonded; electrochemical one-electron reduction potentials of these adducts are shifted by ca. 0.1 V to more negative values for each added group.

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页码：2287 / 2288

页数：2

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