Experimental and theoretical determination of rotational-translational state-to-state rate constants for N2:He collisions at low temperature (3<T<20 K)

We present an experimental determination of state-to-state rotational-translational (RT) rate constants of N-2:He collisions in the vibrational ground state as a function of temperature in the range 3<T<20 K. Raman spectroscopy in supersonic expansions of N-2/He mixtures is used to determine the primary data that, together with the N-2:N-2 state-to-state RT rates previously determined [Ramos et al., Phys. Rev. A 66, 022702 (2002)], are needed to solve the master equation according to a procedure that does not impose any particular scaling law. We also report first principle calculations of the N-2:He state-to-state RT rate constants performed using the full three-dimensional potential energy surface of Reid [J. Chem. Phys. 107, 2329 (1997)], in the 3<T<300 K temperature range. The coupled-channel method, and the coupled-states approximation, were applied in the low (0-610 cm(-1)) and in the high (610-1500 cm(-1)) energy limits, respectively. A good agreement between theoretical and experimental results is found in the temperature range where comparison is possible. (C) 2003 American Institute of Physics.