Aryloxide-based multidentate ligands for early transition metals and f-element metals

被引：62

作者：

Kawaguchi, H ^{[1
]}

Matsuo, T ^{[1
]}

机构：

[1] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448787, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

aryloxide complexes; multidentate ligands; chelate effect; early transition metals; f-element metals;

D O I：

10.1016/j.jorganchem.2004.08.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article presents an overview of the chemistry of early transition metal and f-element complexes stabilized by aryloxide-based multidentate ligands. Preparations and reactivity studies of these compounds are discussed. The presence of the bridging units in this ligand system imposes a strong geometry constraint to the aryloxide groups, which leads the way to novel patterns of structure and reactivity. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4228 / 4243

页数：16

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