The fragment bis(acetylacetonato)ruthenium:: a meeting-point of coordination and organometallic chemistry

被引：24

作者：

Bennett, MA ^{[1
]}

Byrnes, MJ ^{[1
]}

Kovácik, I ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

ruthenium; acetylacetonate; redox behaviour; alkene complexes; alkyne complexes; nucleophilic attack;

D O I：

10.1016/j.jorganchem.2004.07.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of [Ru(acac)(3)] with zinc in THF/H2O Provides a range of coordination and organometallic complexes containing Ru-II(acac)(2), whose chemistry is reviewed. Most of these compounds, including those containing alkenes, undergo reversible one-electron oxidation to their Ru-III(acac)(2) counterparts, and the alkene-ruthenium(III) cations have been detected by spectroclectro-chemistry. The cations derived from the chelate N-donor ligands o-CH2=CHC6H4NMe2 and o-PhC-=CC6H4NMe2 have been isolated and structurally characterized. Comparison of the metrical data establishes that, whereas the alkene is less firmly bound to Ru-III than to Ru-II, the alkyne is bound about as strongly to Ru-III as to Ru-II. Some uncharged nucleophiles (pyridine, diethylamine, PPh3) react with the cationic Ru-III complexes to give unusual, paramagnetic Ru-III-C sigma-bonded chelate complexes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4463 / 4474

页数：12

共 88 条

[11] Synthesis, structure, and fluxional behavior of bis(cyclooctatetraene)ruthenium(0) and its derivatives [J].

Bennett, MA ;

Neumann, H ;

Willis, AC ;

Ballantini, V ;

Pertici, P ;

Mann, BE .

ORGANOMETALLICS, 1997, 16 (13) :2868-2878

[12] Alkene complexes of divalent and trivalent ruthenium stabilized by chelation. Dependence of coordinated alkene orientation on metal oxidation state [J].

Bennett, MA ;

Heath, GA ;

Hockless, DCR ;

Kovacik, I ;

Willis, AC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) :932-941

[13] Chelate alkyne complexes of divalent and trivalent ruthenium stabilized by N-donor ligation [J].

Bennett, MA ;

Heath, GA ;

Hockless, DCR ;

Kovacik, I ;

Willis, AC .

ORGANOMETALLICS, 1998, 17 (26) :5867-5873

[14]

BENNETT MA, UNPUB

[15]

BENNETT MA, 2004, IN PRESS INORG CHIM

[16]

BURSTEN BE, 1988, PROG INORG CHEM, V36, P393

[17] LIGAND ADDITIVITY - APPLICATIONS TO THE ELECTROCHEMISTRY AND PHOTO-ELECTRON SPECTROSCOPY OF D6 OCTAHEDRAL COMPLEXES [J].

BURSTEN, BE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (05) :1299-1304

[18] REACTIONS OF SOME METAL CARBONYLS WITH CHELATING COMPOUNDS CONTAINING ACTIVE PROTONS ESPECIALLY SCHIFFS BASES [J].

CALDERAZZO, F ;

FLORIANI, C ;

HENZI, R ;

LEPLATTE.F .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (09) :1378-+

[19] Characterization and reactions of previously elusive 17-electron cations:: Electrochemical oxidations of (C6H6)Cr(CO)3 and (C5H5)Co(CO)2 in the presence of [B(C6F5)4]- [J].

Camire, N ;

Nafady, A ;

Geiger, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) :7260-7261

[20] COORDINATION CHEMISTRY OF STIBINE AND BISMUTHINE LIGANDS [J].

CHAMPNESS, NR ;

LEVASON, W .

COORDINATION CHEMISTRY REVIEWS, 1994, 133 :115-217

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