Unprecedented (3,9)-connected (42.6)3(46.621.89) net constructed by trinuclear mixed-valence cobalt clusters

被引:138
作者
Zhang, Xian-Ming [1 ]
Zheng, Yan-Zhen
Li, Cui-Rui
Zhang, Wei-Xiong
Chen, Xiao-Ming
机构
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
[2] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synth Chem, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
关键词
D O I
10.1021/cg070038o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co-3(OH)(pdc)(3)]center dot H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) topology in which hydroxycentered mixed-valence Co-3(OH)(CO2)(6) clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.
引用
收藏
页码:980 / 983
页数:4
相关论文
共 46 条
[1]   RELATIONS BETWEEN BOND LENGTHS AND BOND STRENGTHS IN OXIDE STRUCTURES [J].
ALLMANN, R .
MONATSHEFTE FUR CHEMIE, 1975, 106 (03) :779-793
[2]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[3]  
2-Z
[4]   Inorganic crystal engineering using self-assembly of tailored building-blocks [J].
Blake, AJ ;
Champness, NR ;
Hubberstey, P ;
Li, WS ;
Withersby, MA ;
Schröder, M .
COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138
[5]  
Blatov V. A., 2004, TOPOS MULTIPURPOSE C
[6]  
Blatov V.A., 2006, IUCR COMPCOMM NEWSLE, V7, P4, DOI DOI 10.1039/B807165A
[7]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[8]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[9]   CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES [J].
CANNON, RD ;
WHITE, RP .
PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 :195-298
[10]   Polycatenation, polythreading and polyknotting in coordination network chemistry [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289