Ruthenium-catalyzed cross-metathesis between diallylsilanes and electron-deficient Olefins

被引:17
作者
BouzBouz, Samir [1 ]
Boulard, Lucie [1 ]
Cossy, Janine [1 ]
机构
[1] ESPCI, CNRS, Chim Organ Lab, F-75231 Paris 5, France
关键词
D O I
10.1021/ol0712632
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Diallysilanes can be selectively coupled with electron-deficient olefins under cross-metathesis (CM) conditions using the Hoveyda-Grubbs catalyst to produce mono- and/or bis-CM compounds in good yield. The formation of the mono- and the bis-CM compounds depends on the nature of the electron-deficient olefin.
引用
收藏
页码:3765 / 3768
页数:4
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