Triethylborane triggered intermolecular domino Michael-aldol three-component coupling reactions

被引：26

作者：

Chandrasekhar, S ^{[1
]}

Narsihmulu, C ^{[1
]}

Reddy, NR ^{[1
]}

Reddy, MS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 12期

关键词：

domino Michael-aldol reaction; triethylborane; three-component coupling;

D O I：

10.1016/S0040-4039(03)00246-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The triethylborane triggered intermolecular domino Michael-aldol reaction is described. Initial triethylborane addition in a Michael fashion to methyl vinyl ketone resulted in a vinylborane which further reacted with an aldehyde to give the aldol product in a one-pot process. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2583 / 2585

页数：3

共 47 条

[31] ZIPPER-MODE CASCADE CARBOMETALLATION FOR CONSTRUCTION OF POLYCYCLIC STRUCTURES [J].

NEGISHI, E .

PURE AND APPLIED CHEMISTRY, 1992, 64 (03) :323-334

[32] Cyclic carbopalladation. A versatile synthetic methodology for the construction of cyclic organic compounds [J].

Negishi, EI ;

Coperet, C ;

Ma, SM ;

Liou, SY ;

Liu, F .

CHEMICAL REVIEWS, 1996, 96 (01) :365-393

[33]

Neuschutz K, 1998, SYNTHESIS-STUTTGART, P227

[34] Transition metal-catalyzed carbocyclizations in organic synthesis [J].

Ojima, I ;

Tzamarioudaki, M ;

Li, ZY ;

Donovan, RJ .

CHEMICAL REVIEWS, 1996, 96 (02) :635-662

[35] INTRAMOLECULAR, STOICHIOMETRIC (LI, MG, ZN) AND CATALYTIC (NI, PD, PT) METALLO-ENE REACTIONS IN ORGANIC-SYNTHESIS [J].

OPPOLZER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (01) :38-52

[36] PALLADIUM-CATALYZED POLYENE CYCLIZATIONS [J].

OVERMAN, LE ;

ABELMAN, MM ;

KUCERA, DJ ;

TRAN, VD ;

RICCA, DJ .

PURE AND APPLIED CHEMISTRY, 1992, 64 (12) :1813-1819

[37]

Paulsen H, 1999, ANGEW CHEM INT EDIT, V38, P3373, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3373::AID-ANIE3373>3.0.CO

[38]

2-F

[39] New three-component synthesis of 1,3-dienes employing nickel catalysis [J].

Qi, X ;

Montgomery, J .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (25) :9310-9313

[40] One-pot synthesis of α-amino phosphonates from aldehydes using lanthanide triflate as a catalyst [J].

Qian, CT ;

Huang, TS .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (12) :4125-4128

← 1 2 3 4 5 →