Room-temperature oxidation of reduced Cu/ZnO surfaces by lattice oxygen diffusion

被引：12

作者：

Ahlers, Jesse A. ^{[1
]}

Grasser, Jordan A. ^{[1
]}

Loveless, Brett T. ^{[1
]}

Muggli, Darrin S. ^{[1
]}

机构：

[1] Univ N Dakota, Dept Chem Engn, Grand Forks, ND 58202 USA

来源：

CATALYSIS LETTERS | 2007年 / 114卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

room temperature; oxidation;

D O I：

10.1007/s10562-007-9065-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

At room temperature in the absence of gas-phase oxygen, reduced Cu on Cu/ZnO extracts oxygen from the ZnO lattice to reoxidize the surface. After 120 min at room temperature, diffusion of lattice oxygen reoxidizes reduced Cu/ZnO to 3% of its completely oxidized state. When gas-phase oxygen is present, it promotes the partial reoxidation of the reduced Cu/ZnO surface at room-temperature.

引用

页码：185 / 191

页数：7

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