Cyclophanes and ladderanes: Molecular targets for supramolecular chemists

被引：30

作者：

Friscic, T ^{[1
]}

MacGillivray, LR ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52245 USA

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 1-2期

关键词：

target-oriented synthesis; supramolecular chemistry; linear template; solid-state reactions; cyclophane; ladderane;

D O I：

10.1080/10610270412331328853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show that principles of supramolecular chemistry applied in the solid state provide a means to conduct target-oriented molecular syntheses. The syntheses are achieved using molecules that function as linear templates. The templates control molecular organization in the solid state by juxtaposing appropriately functionalized olefins for [2 + 2] photodimerization. We reveal that the linear templates can be used to construct a [2.2]cyclophane and [n]-ladderanes (where n = 3,5) as targets.

引用

页码：47 / 51

页数：5

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