Covalent immobilization of a TiW5 polyoxometalate on derivatized silicon surfaces

被引：99

作者：

Errington, RJ ^{[1
]}

Petkar, SS ^{[1
]}

Horrocks, BR ^{[1
]}

Houlton, A ^{[1
]}

Lie, LH ^{[1
]}

Patole, SN ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 08期

关键词：

alkoxides; polyoxometalates; surface chemistry; titanium; tungsten;

D O I：

10.1002/anie.200461065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent ties: The polyoxometalate (nBu4N)3[(MeO) TiW5O18] is easily anchored to alkanol-functionalized surfaces of porous and single-crystal silicon (see picture, polyhedra: polyoxometalate, dark blue: Si surface). Scanning tunneling microscopy reveals the growth of 35-50 nm diameter islands on functionalized Si(111), which suggests that the immobilized polyoxometalates act as nucleation sites for electrostatic aggregation. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1254 / 1257

页数：4

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