Propeller-shaped chain and 2D grid coordination polymers with the host molecule cyclotriveratrylene and (CB9H5Br5)-

被引：17

作者：

Ahmad, R ^{[1
]}

Hardie, MJ ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 11期

关键词：

D O I：

10.1039/b405031b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The host molecule cyclotriveratrylene (CTV) forms coordination polymers with the Group 1 metals K 1 and Rb+ and with the carbaborane (CB9H5Br5)- as the counter-anion. [K(CTV)(2)](CB9H5Br5)(CF3CH2OH)(2) has a chain structure with an unusual propeller-shaped cross-section, while [Rb(CTV)(CB9H5Br5)(CH3CN)] has a two-dimensional grid structure of distorted hexagonal topology and is one of the few examples of a rubidium acetonitrile complex.

引用

页码：1315 / 1319

页数：5

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